| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Modest Jonathan Mero | Ambassador | 2017 - 2020 |
| 2 | H.E. Tuvako Nathaniel Manongi | Ambassador | 2012 - 2017 |
| 3 | H.E. Ombeni Y. Sefue | Ambassador | 2010 - 2012 |
| 4 | H.E. Dr. Augustine P. Mahiga | Ambassador | 2003 - 2010 |
| 5 | H.E. Daudi N. Mwakawago | Ambassador | 1994 - 2003 |
| 6 | H.E. Anthony Balthazar Nyaki | Ambassador | 1989 - 1994 |
| 7 | H.E. Mohamed A. Foum | Ambassador | 1984 - 1986 |
| 8 | H.E. Paul Milyango Rupia | Ambassador | 1981 - 1984 |
| 9 | H.E. Dr. Wilbert Kumalija Chagula | Ambassador | 1986 - 1989 |
| 10 | H.E. Dr. Salim Ahmed Salim | Ambassador | 1970 - 1980 |
| 11 | H.E. Akili B.C. Daniel | Ambassador | 1968 - 1970 |
| 12 | H.E. John Samuel Malecela | Ambassador | 1964 - 1968 |
| 13 | H.E. Erasto Andrew Mbwana Mang’enya | Ambassador | 1963 - 1964 |
| 14 | H.E. Asanterabi Zephaniah Nsilo Swai | Ambassador | 1962 - 1963 |
| 15 | H.E. Vedastus Kyalakishaija Kyaruzi | Ambassador | 1962 |
